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XANES Spectroscopy Study of Pb(Ti, Zr)O3 Ferroelectric Thin Films
| Content Provider | Semantic Scholar |
|---|---|
| Author | Mandeljc, Mira Kosec, Marija Gabuda, Svyatoslav P. Kozlova, Svetlana G. Erenburg, Simon Bausk, N. V. |
| Copyright Year | 2003 |
| Abstract | Thin films of zirconium-rich perovskites Pb1 − 3x/2La x Ti0.35Zr0.65O3(PLZT; x = 0.095) and PbTi0.7Zr0.3O3 were studied using X-ray absorption near-edge structure (XANES) spectroscopy. Is shown, that slow crystallization of the system is accompanied by essential change of PbL(3)-edge fine structure indicating that perovskite thin film band structure is sensitive of Ti/Zr ratio. The same results were found in the samples of the same composition with addition of 30% mol of PbO. The evidence for stereo active 6s2 lone-pair is discussed. |
| Starting Page | 191 |
| Ending Page | 199 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1080/10584580490899073 |
| Volume Number | 67 |
| Alternate Webpage(s) | https://arxiv.org/pdf/cond-mat/0312559v1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1080/10584580490899073 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |