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Clustering, conductor-insulator transition and phase separation of an ultrasoft model of electrolytes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Coslovich, Daniele Hansén, J. Kahl, Gerhard |
| Copyright Year | 2011 |
| Abstract | We investigate the clustering and phase separation of a model of ultrasoft, oppositely charged macroions by a combination of Monte Carlo and Molecular Dynamics simulations. Static and dynamic diagnostics, including the dielectric permittivity and the electric conductivity of the model, show that ion pairing induces a sharp conductor-insulator transition at low temperatures and densities, which impacts the separation into dilute and concentrated phases below a critical temperature. Preliminary evidence is presented for a possible tricritical nature of the phase diagram of the model. |
| Starting Page | 1690 |
| Ending Page | 1693 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C0SM01090A |
| Volume Number | 7 |
| Alternate Webpage(s) | http://smt.tuwien.ac.at/extra/publications/papers/2011/clustering.pdf |
| Alternate Webpage(s) | http://tph.tuwien.ac.at/smt/extra/publications/papers/2011/clustering.pdf |
| Alternate Webpage(s) | https://arxiv.org/pdf/1101.2400v1.pdf |
| Alternate Webpage(s) | http://www.cms.tuwien.ac.at/media/pdf/publications/sm-7-1690-2011.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |