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Multicomponent metal-ligand self-assembly.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yoshizawa, Michito Kusukawa, Takahiro Fujita, Makoto |
| Copyright Year | 2002 |
| Abstract | Self-assembly of pre-designed organic ligands with transition metal atoms is a powerful method for construction of novel supramolecular architectures. Particularly, various discrete 3-D hollow structures such as cages, cones, capsules and boxes have been obtained by multicomponent self-assembly of exo-multidentate ligands with cis-protected square planar metal complexes, [(L)M](NO(3))(2) (where L is ethylenediamine or 2,2'-bipyridine and M is Pd or Pt). Furthermore, these hollow structures act as molecular flasks to encapsulate guest molecules and regulate/promote specific reactions; for example, oligomerization of silanetriols and [2+2] intermolecular photodimerization of olefins. |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/S1367-5931(02)00358-7 |
| PubMed reference number | 12470728 |
| Journal | Medline |
| Volume Number | 6 |
| Issue Number | 6 |
| Alternate Webpage(s) | http://hysz.nju.edu.cn/sunwy/publication/2002-Sun-COCB.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/S1367-5931%2802%2900358-7 |
| Journal | Current opinion in chemical biology |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
