NDLI: Single‐Chain Polymer Nanoparticles via Non‐Covalent and Dynamic Covalent Bonds

Content Provider	Semantic Scholar
Author	Sanchez-Sanchez, Ana Pomposo, José A.
Copyright Year	2014
Abstract	The added value behind reversible bonds is the possibility to develop responsive structurally dynamic materials, which can adapt their constitution and, hence, properties to external stimuli. In recent years, much effort has been devoted to the design and synthesis of single-chain polymer nanoparticles (SCNPs) that can be reversibly assembled or disassembled in response to external environmental changes or that can adapt even their structure through simple exchange reactions. Here, the evolution of the relatively new field of responsive SCNPs constructed via non-covalent, or supramolecular, interactions, and “dynamic” covalent bonds is described in detail. The main reversible bonds commonly used in supramolecular polymer chemistry and dynamic covalent materials are summarized. A detailed description of the current reported routes to reversible unimolecular polymer nanoparticles is provided. Finally, future prospects of SCNPs constructed via supramolecular interactions and dynamic bonds are detailed.
Starting Page	11
Ending Page	23
Page Count	13
File Format	PDF HTM / HTML
DOI	10.1002/ppsc.201300245
Volume Number	31
Alternate Webpage(s)	http://digital.csic.es/bitstream/10261/108723/5/Dynamic%20Covalent%20Bonds.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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