Recent Advances in Direct Catalytic Dehydrative Substitution of Alcohols

Content Provider	Semantic Scholar
Author	Dryzhakov, Marian Richmond, Edward Moran, Joseph
Copyright Year	2016
Abstract	This review describes methods for the direct catalytic dehydrative substitution of alcohols in the absence of stoichiometric activating agents, excluding methods that involve transfer hydrogenation. Although some earlier literature is discussed, this review mainly covers literature published from 2010 through August 2015. 1 Introduction 2 SN1-Type Reactivity 2.1 π-Activated Alcohols 2.1.1 Benzylic Alcohols 2.1.2 Allylic Alcohols 2.1.3 Propargylic Alcohols 2.2 Aliphatic Alcohols 2.3 Chemoselectivity Considerations 3 Stereospecific Methods 4 Enantioselective Methods 4.1 Enantioinduction via Transient Chiral Nucleophiles 4.1.1 Nucleophilic Capture of Cationic Intermediates 4.1.2 Nucleophilic Capture of Transition-Metal-Stabilized Intermediates 4.2 Enantioinduction via Transient Chiral Nucleophiles 4.3 Enantioinduction via Synergistic Chiral Catalysis 4.4 Enantioinduction via Bifunctional Catalysis 5 Conclusion and Outlook
Starting Page	935
Ending Page	959
Page Count	25
File Format	PDF HTM / HTML
DOI	10.1055/s-0035-1560396
Alternate Webpage(s)	http://wxjs.chinayyhg.com/upload/Files/20160825125047727/0935-0959.pdf
Alternate Webpage(s)	https://doi.org/10.1055/s-0035-1560396
Volume Number	48
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article