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Preparation, structure, and magnetic interaction of a Mn(hfac)2-bridged [2-(3-pyridyl)(nitronyl nitroxide)-Mn(hfac)2]2 chain complex.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Okada, Keiji Beppu, Shiori Tanaka, Koichiro Kuratsu, Masato Furuichi, Kimiaki Kozaki, Masatoshi Suzuki, Shuichi Shiomi, Daisuke Sato, Kazunobu Takui, Takeji Kitagawa, Yasutaka Yamaguchi, Kizashi |
| Copyright Year | 2007 |
| Abstract | A new one-dimensional chain complex, Mn(hfac)(2)-bridged [2-(3-pyridyl)(nitronyl nitroxide)Mn(hfac)(2)](2), was prepared and its structure and magnetic properties were elucidated; the complex exhibited a large antiferromagnetic interaction of J(1)=-185 K between the three Mn(ii) atoms and the two nitronyl nitroxides to give S=13/2 spin units and a small ferromagnetic interaction of J(3)'=+0.02 K between these spin units at low temperatures (50-1.9 K), compatible with the theoretical analysis for model compounds. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/b618682c |
| PubMed reference number | 17563804 |
| Journal | Medline |
| Volume Number | 24 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/b6/b618682c/b618682c.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/b618682c |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |