NDLI: Microporous, tetraarylethylene-based polymer networks generated in a reductive polyolefination process

Content Provider	Semantic Scholar
Author	Preis, Eduard Dong, Wenyue Brunklaus, Gunther Scherf, Ullrich
Copyright Year	2015
Abstract	Microporous Polymer Networks (MPNs) that contain aggregate-induced emission (AIE) active tetraphenylethylene (TPE) or other tetraarylethylene units have been generated in a reductive polyolefination process starting from four different tris(α,α-dichlorobenzyl)arene derivatives with dicobalt octacarbonyl or chromium(II)acetate as reductive olefination agents. Microporosity with moderately high BET surface areas up to 500 m2 g−1 could be combined with high solid state photoluminescence quantum yields up to 25.3% for polymer network P4. This unique combination should be promising for applications as optical solid state sensors, especially for MPNs with electron-deficient triazine core units.
Starting Page	1582
Ending Page	1587
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/C4TC02664K
Volume Number	3
Alternate Webpage(s)	https://www.makro.uni-wuppertal.de/fileadmin/Chemie/makromolekularchemie/Poster/2015/Eddi_Preis_York_2015.pdf
Alternate Webpage(s)	http://www.rsc.org/suppdata/tc/c4/c4tc02664k/c4tc02664k1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C4TC02664K
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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