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Transition metal complexes with thiosemicarbazide-based ligands. Part 49. New complexes of iron(III) with deprotonated tridentate Schiff base - pyridoxal derivatives
| Content Provider | Semantic Scholar |
|---|---|
| Author | Jovanović, Ljiljana S. Jevtovic, Violeta S. Leovac, Vukadin M. Bjelica, Luka J. |
| Copyright Year | 2005 |
| Abstract | Three new bis(ligand) iron(III) complexes were prepared with the depro- tonated ONX ligands (X = O,S,N), pyridoxal semi-, thiosemi- and S-methylisothio- semicarbazones (H 2 L 1 ,H 2 L 2 and H 2 L 3 , respectively) of the formulas Fe(HL 1,2 )L 1,2. 4H2 Oa ndFe(HL 3 )2OAc . 2H2O. The compounds were characterized by elemental analysis, conductometric and magnetochemical measurements, as well as by IR and UV-vis spectra. Detailed voltammetric investigations were carried out in DMF solu- tions in the presence of several supporting electrolytes to study the nature of the electrochemical processes and solution equilibria. |
| Starting Page | 187 |
| Ending Page | 200 |
| Page Count | 14 |
| File Format | PDF HTM / HTML |
| DOI | 10.2298/jsc0502187j |
| Volume Number | 70 |
| Alternate Webpage(s) | http://www.doiserbia.nb.rs/img/doi/0352-5139/2005/0352-51390502187J.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |