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Chemo- and Diastereoselective N-Heterocyclic Carbene-Catalyzed Cross-Benzoin Reactions Using N-Boc-α-amino Aldehydes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Haghshenas, Pouyan Gravel, Michel |
| Copyright Year | 2016 |
| Abstract | N-Boc-α-amino aldehydes are shown to be excellent partners in cross-benzoin reactions with aliphatic or heteroaromatic aldehydes. The chemoselectivity of the reaction and the facial selectivity on the amino aldehyde allow cross-benzoin products to be obtained in good yields and good diastereomeric ratios. The developed method is utilized as the key step in a concise total synthesis of d-arabino-phytosphingosine. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/acs.orglett.6b02123 |
| PubMed reference number | 27574804 |
| Journal | Medline |
| Volume Number | 18 |
| Issue Number | 18 |
| Alternate Webpage(s) | https://s3-eu-west-1.amazonaws.com/pstorage-acs-6854636/5906664/ol6b02123_si_001.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/acs.orglett.6b02123 |
| Journal | Organic letters |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
