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Synthesis of Substituted Piperidines via Cationic Palladium(II)-Catalyzed Reductive Coupling of N-Tosyl-Tethered Alkynones
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Xiaojuan Han, Xiuling Hu, Zhiyong Lu, Xiyan |
| Copyright Year | 2017 |
| Abstract | A cationic palladium(II) complex catalyzed reductive coupling of N -tosyl-tethered alkynones for the synthesis of functionalized piperidines was successfully developed. This reaction was initiated by hydropalladation of the alkyne and quenched by addition to the intramolecular carbonyl group. The substituent on the alkyne is key to the reaction. |
| Starting Page | 4687 |
| Ending Page | 4692 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1055/s-0036-1588803 |
| Alternate Webpage(s) | https://www.thieme-connect.de/media/synthesis/201720/supmat/sup_ss-2017-c0141-st_10-1055_s-0036-1588803.pdf |
| Alternate Webpage(s) | https://doi.org/10.1055/s-0036-1588803 |
| Volume Number | 49 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |