NDLI: Isoquinoline-based Werner clathrates with xylene isomers: aromatic interactions vs. molecular flexibility.

Content Provider	Semantic Scholar
Author	Wicht, Merrill Margaret Báthori, Nikoletta B. Nassimbeni, Luigi R.
Copyright Year	2015
Abstract	The crystal structures of the Werner clathrates Ni(NCS)2(isoquinoline)4 (H) with para-xylene (px), meta-xylene (mx) and ortho-xylene (ox) have been elucidated. The kinetics of thermal decomposition of the three inclusion compounds were performed using the isothermal technique of Flynn and Wall. Selectivity of H for the xylene isomers was determined for both the liquid and vapour phase binary mixtures of the xylenes. The chosen ligand has a larger aromatic system to improve the possible π interactions between H and the selected guests. The planarity of the isoquinoline ligand causes H rigidity and its selectivity was compared to a related Werner complex containing the more flexible 4-phenylpyridine.
File Format	PDF HTM / HTML
DOI	10.1039/c5dt00084j
PubMed reference number	25773872
Journal	Medline
Volume Number	44
Issue Number	15
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/dt/c5dt00084j/c5dt00084j1.pdf
Alternate Webpage(s)	http://pubs.rsc.org/en/content/getauthorversionpdf/C5DT00084J
Journal	Dalton transactions
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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