NDLI: A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds† †Electronic supplementary information (ESI) available: Full details relating to experimental, crystallographic and computational procedures. CCDC 1901003–1901008. For ESI and crystallographic data in CIF or other electr

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A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds† †Electronic supplementary information (ESI) available: Full details relating to experimental, crystallographic and computational procedures. CCDC 1901003–1901008. For ESI and crystallographic data in CIF or other electr

Content Provider	Semantic Scholar
Author	Roy, Matthew M. D. Ferguson, Michael J. McDonald, Robert Zhou, Yuqiao Rivard, Eric
Copyright Year	2019
Abstract	The facile synthesis of a rare two-coordinate acyclic silylene (R2Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly σ-donating hypersilyl group [Si(SiMe3)3]- is reported. This vinyl-substituted silylene exhibits an excellent combination of prolonged thermal stability along with high reactivity towards small molecules. Despite being stable for months in solution, the reactivity of this new silylene is manifest in its ambient temperature activation of strong B-H, Si-Cl, C-O, P-P and C-H bonds.
Starting Page	6476
Ending Page	6481
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c9sc01192g
PubMed reference number	31341599
Journal	Medline
Volume Number	10
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/sc/c9sc01192g/c9sc01192g1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c9sc01192g
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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