NDLI: Copper-catalyzed intermolecular oxidative trifluoromethyl-arylation of styrenes with NaSO2CF3 and indoles involving C-H functionalization.

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Copper-catalyzed intermolecular oxidative trifluoromethyl-arylation of styrenes with NaSO2CF3 and indoles involving C-H functionalization.

Content Provider	Semantic Scholar
Author	Min, Man-Yi Song, Ren-Jie Ouyang, Xuan-Hui Li, Jin-Heng
Copyright Year	2019
Abstract	A new copper-catalyzed three-component oxidative 1,2-trifluoromethylarylation of styrenes with NaSO2CF3 and indoles involving aryl C-H bond functionalization is described. This reaction is initiated by single electron transfer upon utilizing TBPB as an oxidant, thus enabling introduction of a CF3 group and an aryl group into the C[double bond, length as m-dash]C bond of alkenes in a single step. This method represents a highly atom and step-economical access to various CF3-substituted 1,1-diarylalkane derivatives in moderate to good yields with good functional group compatibility.
Starting Page	3646
Ending Page	3649
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/c9cc00469f
PubMed reference number	30849147
Journal	Medline
Volume Number	55
Issue Number	25
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/cc/c9cc00469f/c9cc00469f1.pdf
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/cc/c9cc00469f/c9cc00469f2.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c9cc00469f
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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