NDLI: Sterically hindered N-heterocyclic carbene/palladium(ii) catalyzed Suzuki-Miyaura coupling of nitrobenzenes.

Content Provider	Semantic Scholar
Author	Chen, Kai Chen, Wei Yi, Xiaofei Chen, Wanzhi Liu, Miaochang Wu, Huayue
Copyright Year	2019
Abstract	Palladium-catalyzed denitrative Suzuki coupling of nitroarenes using 2-aryl-5-(2,4,6-triisopropylphenyl)-2,3-imidazolylidene[1,5-a]pyridines as the ligands is described. The key to success is the use of the NHC ligands which show strong donating ability and suitable steric hindrance allowing the successful oxidative addition of Ar-NO2 bonds. Both aromatic and aliphatic boronic acids are tolerated, and a variety of biphenyls and alkylarenes were obtained in good to excellent yields.
File Format	PDF HTM / HTML
DOI	10.1039/c9cc04634h
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/cc/c9cc04634h/c9cc04634h1.pdf
PubMed reference number	31332404
Alternate Webpage(s)	https://doi.org/10.1039/c9cc04634h
Journal	Medline
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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