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Synthesis and catalytic activity of ionic palladium N-heterocyclic carbene complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yaşar, Sedat Oezdemir, Ismail |
| Copyright Year | 2019 |
| Abstract | The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC:N -heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr3 ]− [NHC] . The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki–Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://journals.tubitak.gov.tr/chem/issues/kim-19-43-6/kim-43-6-9-1907-74.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |