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Efficient electron transport in ZnO nanowire/nanoparticle dye-sensitized solar cells via continuous flow injection process
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Liang-Yih Yin, Yu-Tung |
| Copyright Year | 2013 |
| Abstract | In this study, a long ZnO nanowire (NW) array was synthesized using a continuous flow injection (CFI) process to replace the conventional multi-batch process. According to electrochemical impedance spectroscopy (EIS) measurements, the diffusion coefficient of the ZnO NW array by a CFI process is higher than that of ZnO NWs using a multi-batch process. In addition, the electron transit time was found to depend on the thickness of the ZnO NW array. To effectively improve the conversion efficiency of ZnO NW dye-sensitized solar cells (DSSCs), a high diffusion coefficient of the ZnO NW array with 1.2 × 10−2 cm2 s−1 was synthesized by an ammonia-assisted CFI process. In addition, ZnO NPs were covered along the ZnO NW array as a ZnO NW/NP photoanode to provide a high dye adsorption area for increasing electron injection flux. In this study, the growth period of ZnO NPs playing a crucial role in the electron transport of the ZnO NW/NP photoanode was demonstrated. A high-efficiency DSSC of 6.8% is achieved using a N719-sensitized ZnO NW/NP photoanode with 25 μm. |
| Starting Page | 8480 |
| Ending Page | 8488 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C3RA22458A |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c3/c3ra22458a/c3ra22458a.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C3RA22458A |
| Volume Number | 3 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |