NDLI: d cascade annulation of unsaturated a-bromocarbonyls with enynals : a facile access to ketones from aldehydes †

Content Provider	Semantic Scholar
Author	Che, Chao Huang, Qianwen Zheng, Hanliang Zhu, Gangguo
Copyright Year	2016
Abstract	A Cu-catalyzed cascade annulation of enynals with alkenyl or alkynyl a-bromocarbonyls for the synthesis of various cyclohexenone-fused polycyclic compounds is described. Up to six new C–C bonds and four new carbocycles can be established in a single reaction, highlighting the high efficiency and step-economics of this protocol. This reaction offers a novel and straightforward entry to the synthesis of ketones featuring the addition of carbon radicals to aldehydes.
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2016/sc/c5sc04980f
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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