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Direct and metal-free arylsulfonylation of alkynes with sulfonylhydrazides for the construction of 3-sulfonated coumarins.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wen, Jiangwei Yang, Daoshan Guo, Mengyuan Wang, Yingying You, Jinmao Wang, Hua |
| Copyright Year | 2015 |
| Abstract | A novel and metal-free procedure has been developed for the construction of 3-sulfonated coumarins via the direct difunctionalization of alkynoates with sulfonylhydrazides. The present protocol, which simply utilizes TBAI as the catalyst and TBHP as the oxidant, provides a convenient and highly efficient approach to construct a series of sulfonated coumarins with high regioselectivity and good functional group tolerance. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c4cc08117j |
| PubMed reference number | 25421259 |
| Journal | Medline |
| Volume Number | 51 |
| Issue Number | 4 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c4/c4cc08117j/c4cc08117j1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C4CC08117J |
| Alternate Webpage(s) | https://doi.org/10.1039/c4cc08117j |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |