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Applicability of Fuoss-Onsager Equation to Electrical Conductances of Dilute Solutions of Triethyl-n-propylammonium Iodide
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ahmad, M. |
| Copyright Year | 2016 |
| Abstract | The electrical conductances of triethyl-n-propylammonium iodide (Et3PrNI) recorded in water (dielectric constant, D = 78), nitrobenzene (D = 34), acetic anhydride (D = 20), t-butano l (D = 17), and benzyl alcohol (D =,13) at 30° have been analysed in terms of Fuosa-Onsager equation. The limiting equivalent conductance, Ao' the ion-size parameter, aO, and the association constant, KA have been computed. The ion-size parameter is found to be independent of the dielectric constant of the medium; the association constants, however, show an exponential relationship whereas walden products show no regular variation. Besides the dielectric constant. the viscosity of the medium has also been found to affect significantly the value of Ao. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://nopr.niscair.res.in/bitstream/123456789/51539/1/IJCA%2017A(2)%20126-129.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
