NDLI: Crystal Structure of a Binuclear Copper(II) Complex with μ-Alkoxo and μ-Pyridonato Bridges. Effect of the Dihedral Angle on the Superexchange Interaction

Content Provider	Semantic Scholar
Author	Nishida, Yuzo Masumoto, Miyuki Mori, Yutaka
Copyright Year	1989
Abstract	The crystal structure of the binuclear copper(II) complex. [Cu2(L)(2-pyridonato)] was determined by X-ray diffraction, where H3(L) represents the Schiff base ligand derived from 1,3-diaminopropane-2-ol and acetylacetone. Two copper(II) ions are bridged by alkoxide and 2-pyridonate groups with a Cu-Cu separation of 3.249(2) Å . Ferromagnetic interaction is found to be operating in this complex, which is attributed to the small dihedral angle (121°) between the two planes containing the copper(II) ion.
Starting Page	307
Ending Page	311
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1515/znb-1989-0311
Volume Number	44
Alternate Webpage(s)	http://zfn.mpdl.mpg.de/data/Reihe_B/44/ZNB-1989-44b-0307.pdf
Alternate Webpage(s)	https://doi.org/10.1515/znb-1989-0311
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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