Disilyne with a silicon – silicon triple bond : A new entry to multiple bond chemistry *

Content Provider	Semantic Scholar
Author	Sekiguchi, Akira
Copyright Year	2008
Abstract	The synthesis, crystal structure, and characterization of a silicon–silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cisand trans-2-butenes and phenylacetylene is also described.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://www.iupac.org/publications/pac/pdf/2008/pdf/8003x0447.pdf
Language	English
Access Restriction	Open
Subject Keyword	Alkalies Crystal structure Metals Metals, Alkali Published Comment Silicon phenylacetylene
Content Type	Text
Resource Type	Article