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Metal-ligand multiple bonds. Oxo, imido and nitrido complexes of ruthenium and osmium
| Content Provider | Semantic Scholar |
|---|---|
| Author | Che, Chi-Ming |
| Copyright Year | 1995 |
| Abstract | Ru=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbons and epoxidation of alkenes . Photoexcitation of trans- dioxoosmium(V1) gives rise to super-oxidizing complexes having EO >2.2 V vs. n.h.e. Some cationic RuZN and OsZN complexes are good model system for study of the mechanism of metal- catalysed oxidation of ammonia to nitrite and activation of diiiitrogen molecule. With 2,3-diamino-2,3-dimethylbutane as ligand, reversible Os(1V)-amide/Os(III)-amine and Ru(V)- imido/Ru(II)-amine redox couplexes are observed. |
| Starting Page | 225 |
| Ending Page | 232 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1351/pac199567020225 |
| Volume Number | 67 |
| Alternate Webpage(s) | http://old.iupac.org/publications/pac/1995/pdf/6702x0225.pdf |
| Alternate Webpage(s) | http://hub.hku.hk/bitstream/10722/45693/1/1433.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |