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Framework variations in Mn(II)–organic coordination polymers: solvent templated formation and characterisation of 1D zigzag and straight chain network isomers
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ma, Cheng-Bing Chen, Changneng Liu, Qiutian |
| Copyright Year | 2005 |
| Abstract | Hydrothermal reaction of manganese carbonate with 4,4′-biphenyldicarboxylic acid (H2bda) and 1,10-phenanthroline (phen) affords coordination polymers, [Mn(bda)(phen)(H2O)]n·npy·nH2O (1·npy·nH2O, 1a), [Mn(bda)(phen)(H2O)]n·2npip (1·2npip, 1b) and [Mn(bda)(phen)]n (2). The polymer 1 crystallizes into either 1D zigzag chain or straight chain structures depending on the crystallisation solvents used, and both of them stack into a 3D guest-filled porous framework via inter-chain interactions, whereas the polymer 2 organizes into a 3D ligand-filled porous coordination framework in the absence of suitable guests. The polymer 1 represents an unusual example of network isomers formed via the templating of structurally dissimilar but closely related organic guests. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B511909J |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ce/b5/b511909j/b511909j.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/B511909J |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
