Loading...
Please wait, while we are loading the content...
Similar Documents
Syntheses of copper(I)cis-1,3,5-tri-iminocyclohexane complexes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Nairn, Alison K. Archibald, Stephen J. Bhalla, Rajiv Boxwell, Clive J. Whitwood, Adrian C. Walton, Paul H. |
| Copyright Year | 2006 |
| Abstract | Copper(I) complexes of the ligand cis-1,3,5-tris(cinnamylideneamino)cyclohexane (L) have been prepared from a versatile precursor complex, [Cu(I)(L)NCMe]BF4, which incorporates a labile acetonitrile ligand that can be exchanged to give a range of new Cu(L)X complexes (where X = Cl, Br, NO2, SPh). 1H NMR spectra and X-ray structures of the Cl, Br and NO2 complexes show L coordinated in a symmetric fashion about the copper centre. The complexes have been further characterised using UV/Visible spectroscopy and cyclic voltammetry. CuLCl shows an electrochemically reversible Cu(I/II) redox couple at 0.51 V (vs. Ag/AgCl) while the CuLNO2 complex shows an analogous quasi-reversible wave at 0.41 V (vs. Ag/AgCl). |
| Starting Page | 1203 |
| Ending Page | 1207 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://espace.library.uq.edu.au/data/UQ_353936/UQ353936_OA.pdf?Expires=1496192235&Key-Pair-Id=APKAJKNBJ4MJBJNC6NLQ&Signature=WtLFz2K3qqLyUOPCPKncTnxc-EQwA~il5YVaRRDywcOZ-K~c9dGAmAovl4gLLnBCsIRElM2JpcjjthlQDF6LrYuJlFH7U7r7uH-cbzKUIDEmWC5VmmA3R~3SblPf2PUDb2IsAudn~pOFIkqNMerWjxDKI5QNaMC40Mn5i~tPRvENw3bpmWM8eu1KxHasmQQjxMAw18K6XfLociHgHv~jih0f9BVFTmfVJhxqaNyztS51NbAvpgkX39fRc9c5DuXc2Q1e-hJ883os0dGoLrwCh1nX83iQzJc7bsKGVktQasPiV3wfaMb14F6cjzF~vw3FSONg0p~apqRhqo5ofsMZrA__ |
| PubMed reference number | 16568189v1 |
| Volume Number | 14 |
| Journal | Dalton transactions |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Bromides Ligands SPHEROCYTOSIS, TYPE 1 (disorder) Silver acetonitrile |
| Content Type | Text |
| Resource Type | Article |