NDLI: Tris(1H-benzimidazol-2-ylmethyl)amine-solvent adducts.

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Tris(1H-benzimidazol-2-ylmethyl)amine-solvent adducts.

Content Provider	Semantic Scholar
Author	Zhang, Xue-Li Zheng, Sheng-Run Liu, Yong-Ru Zheng, Xiang-Li Su, Cheng-Yong
Copyright Year	2005
Abstract	The tris(1H-benzimidazol-2-ylmethyl)amine (ntb) molecule crystallizes in different solvent systems, resulting in two kinds of adduct, namely the monohydrate, C24H21N7.H2O or ntb.H2O, (I), and the acetonitrile-methanol-water (1/0.5/1.5) solvate, C24H21N7.C2H3N.0.5CH4O.1.5H2O or ntb.1.5H2O.0.5MeOH.MeCN, (II). In both cases, ntb adopts a tripodal mode to form hydrogen bonds with a solvent water molecule via two N-H...O and one O-H...N hydrogen bond. In (I), the ntb.H2O adduct is further assembled into a two-dimensional network by N-H...N and O-H...N hydrogen bonds, while in (II), a double-stranded one-dimensional chain structure is assembled via N-H...O and O-H...O hydrogen bonds, with the acetonitrile molecules located inside the cavities of the chain structure.
Starting Page	39
Ending Page	45
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1107/S0108270105023553
PubMed reference number	16143773
Journal	Medline
Volume Number	61
Part	9
Alternate Webpage(s)	http://journals.iucr.org/c/issues/2005/09/00/fg1867/fg1867.pdf
Alternate Webpage(s)	https://doi.org/10.1107/S0108270105023553
Journal	Acta crystallographica. Section C, Crystal structure communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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