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Mechanistic insight into the preactivation of a modern palladium catalyst precursor in phosphine-free Heck reactions
| Content Provider | Semantic Scholar |
|---|---|
| Author | Petrović, Zorica D. Marković, Svetlana Simijonović, Dušica Petrovic, V. Aleksandar |
| Copyright Year | 2009 |
| Abstract | The use of well-defined trans-dichlorobis(diethanolamine-N)palladium(II) complex (trans-[PdCl2(DEA)2]) as a new, modern, and effective Heck precatalyst is reported. The mechanism of the key, initial steps of the reaction, i.e., the formation of the Pd(0) complex, is examined using density functional theory.Graphical abstract |
| Starting Page | 371 |
| Ending Page | 374 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/s00706-008-0035-0 |
| Volume Number | 140 |
| Alternate Webpage(s) | https://www.npao.ni.ac.rs/files/2337/Monatsh_Chem1_2008_str_2009_66893.pdf |
| Alternate Webpage(s) | https://doi.org/10.1007/s00706-008-0035-0 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |