NDLI: Iridium-Catalyzed C4-Alkylation of 2,6-Di-tert-butylphenol by Using Hydrogen-Borrowing Catalysis

Content Provider	Semantic Scholar
Author	Frost, James R. Cheong, Choon Boon Donohoe, Timothy J.
Copyright Year	2016
Abstract	An iridium-catalyzed hydrogen-borrowing process has been developed whereby 2,6-di-tert-butylphenol can be alkylated at the C4-position by using a range of primary alcohols (11 examples, 40–93% yield). Following this, a selection of the products obtained underwent retro-Friedel–Crafts reactions to provide para-substituted phenols, which could potentially undergo further synthetic manipulations.
Starting Page	910
Ending Page	916
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1055/s-0035-1561439
Volume Number	49
Alternate Webpage(s)	https://www.thieme-connect.de/media/synthesis/201704/supmat/sup_ss-2016-z0210-op_10-1055_s-0035-1561439.pdf
Alternate Webpage(s)	https://www.thieme-connect.com/products/ejournals/pdf/10.1055/s-0035-1561439.pdf
Alternate Webpage(s)	https://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0035-1561439.pdf
Alternate Webpage(s)	https://doi.org/10.1055/s-0035-1561439
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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