NDLI: Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]

Content Provider	Semantic Scholar
Author	Alegria, Elisabete C. B. A. Cunha, Sónia M. P. R. M. Martins, Luísa Silva, M. F. C. Guedes Da Pombeiro, Armando J. L.
Copyright Year	2004
Abstract	The bis(cyanoimide) complex trans-[Mo(NCN)2(dppe)2] (1, dppe = Ph2PCH2CH2PPh2) is susceptible of electrophilic attack to form the acylated and aroylated derivatives trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et 2a or Ph 2b). Herein, we report a preliminary study on the electrochemical behaviour of complexes 2 and the derivative trans-[Mo(NCN)Cl(dppe)2][BF4] 3, as investigated by cyclic voltammetry (CV) and controlled-potential electrolysis (CPE), what has allowed a comparison of the electrondonor ability of the ligands.
Starting Page	19
Ending Page	23
Page Count	5
File Format	PDF HTM / HTML
DOI	10.4152/pea.200401019
Volume Number	22
Alternate Webpage(s)	http://www.peacta.org/articles_upload/PEA200422119.pdf
Alternate Webpage(s)	https://doi.org/10.4152/pea.200401019
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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