NDLI: Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II)

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Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II)

Content Provider	Semantic Scholar
Author	Arunkashi, H. K. Jeyaseelan, Selvi Vepuri, Suresh Babu Revanasiddappa, Hosakere D. Devarajegowda, H. C.
Copyright Year	2010
Abstract	The asymmetric unit of the title salt, (C(16)H(20)N(3)S)(2)[Co(NCS)(4)], comprises one monovalent isothio-pendylium cation and one-half of a divalent thio-cyanatocobaltate(II) anion (2 symmetry). The central thia-zine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the mean plane of 0.272 (1) and 0.2852 (8) Å for the N and S atoms. The mol-ecular structure of the cation is stabilized by an intra-molecular N-H⋯N hydrogen bond. Within the complex anion, the Co(II) atom is tetra-hedrally surrounded by four N atoms of the thio-cyanate ligands. π-π stacking, with a distance of 3.7615 (10) Å between the centroids of benzene and pyridine rings, helps to consolidate the packing.
Starting Page	m772
Ending Page	m773
Page Count	2
File Format	PDF HTM / HTML
DOI	10.1107/S1600536810021367
Alternate Webpage(s)	http://eprints.uni-mysore.ac.in/14477/1/Bis%5BN,N-dimethyl-1-(10H-pyrido%5B3,2-b%5D%5B1,4%5Dbenzothiazin-10-yl)propan-2-aminium%5D%20tetrakis(thiocyanato-%5Bkappa%5DN)cobaltate(II).pdf
Alternate Webpage(s)	http://journals.iucr.org/e/issues/2010/07/00/wm2356/wm2356.pdf
Alternate Webpage(s)	http://eprints.uni-mysore.ac.in/4973/1/Bis%5BN,N-dimethyl-1-(10H-pyrido%5B3,2-b%5D.pdf
Alternate Webpage(s)	http://ftp.ncbi.nlm.nih.gov/pub/pmc/39/62/e-66-0m772.PMC3006707.pdf
PubMed reference number	21587702
Alternate Webpage(s)	https://doi.org/10.1107/S1600536810021367
Journal	Medline
Volume Number	66
Journal	Acta crystallographica. Section E, Structure reports online
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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