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Resonance-assisted hydrogen bonding induced nucleophilic addition to hamper ESIPT: ratiometric detection of cyanide in aqueous media.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Goswami, Shymaprosad Manna, Abhishek Paul, Sima Das, Avijit Kumar Aich, Krishnendu Nandi, Prasanta Kr. |
| Copyright Year | 2013 |
| Abstract | For ratiometric "naked eye" detection of CN(-), an ESIPT exhibiting benzothiazole receptor (BHI) is designed having one aldehyde group ortho and the other aldehyde para to the OH group respectively. Due to RAHBs, the ortho aldehyde group is highly reactive undergoing nucleophilic cyanide addition selectively, which hampered ESIPT. This is also supported by DFT and TD-DFT calculations. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c3cc39256b |
| PubMed reference number | 23450121 |
| Journal | Medline |
| Volume Number | 49 |
| Issue Number | 28 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c3/c3cc39256b/c3cc39256b.pdf |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |