NDLI: Darstellung und Reaktionen von 2-Isocyanato-2-alkensäureestern (Aminosäuren ; 18)

Content Provider	Semantic Scholar
Author	Effenberger, Franz Prof Dr Kuehlwein, Juergen Dipl-Chem Baumgartner, Christian
Copyright Year	1994
Abstract	2-Isocyanato-2-alkenoates 3 were obtained in good yields by the perrhenate-catalyzed decomposition of 2-azidoalkanoates 1 in the presence of diphosgene (2a) or phosgene (2b). Methyl 2-azidopropionate (1h) reacts to give a mixture of methyl 2-isocyanato-2-propenoate (3h) and methyl 2-chloro-2-isocyanatopropionate (4). The addition product 4 could easily be converted into 3h by elimination of HCl with triethylamine at 0°C. With benzyl alcohol (5a) and tert-butyl alcohol (5b) the isocyanates 3 react smoothly to give the corresponding Z- or Boc-protected 2,3-didehydroamino acid esters 6 and 7, respectively. The acrylic acid derivative 3h reacts as dienophile with various dienes to yield the Diels-Alder adducts 8-10.
File Format	PDF HTM / HTML
DOI	10.18419/opus-1177
Alternate Webpage(s)	http://elib.uni-stuttgart.de/bitstream/11682/1194/1/eff253.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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