NDLI: tert-Butyl nitrite (TBN) as the N atom source for the synthesis of substituted cinnolines with 2-vinylanilines and a relevant mechanism was studied.

Content Provider	Semantic Scholar
Author	Pang, Xiaobo Zhao, Lianbiao Zhou, Dagang He, Ping Yong An, Zhenyu Ni, Ji Xiang Yan, Rulong
Copyright Year	2017
Abstract	A green method to synthesize cinnolines by 6π electrocyclic reaction with alkenyl amines and TBN has been developed. TBN plays a dual role both as a nitrogen atom source and an oxidant in this procedure. Relevant mechanism experiments reveal that the reaction proceeds through electrocyclic reaction and with diazo hydroxide as a key intermediate.
Starting Page	6318
Ending Page	6322
Page Count	5
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://www.rsc.org/suppdata/c7/ob/c7ob01553d/c7ob01553d1.pdf
PubMed reference number	28730188v1
Alternate Webpage(s)	https://doi.org/10.1039/c7ob01553d
DOI	10.1039/c7ob01553d
Journal	Organic & biomolecular chemistry
Volume Number	15
Issue Number	30
Language	English
Access Restriction	Open
Subject Keyword	Aluminum Hydroxide 40 MG/ML / Magnesium Hydroxide 40 MG/ML / Simethicone 4 MG/ML Oral Suspension Amines Dual Hydroxide Ion Nitrogen 99 % Gas for Inhalation Oxidants tert-Butyl Alcohol
Content Type	Text
Resource Type	Article

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