NDLI: Design and sterospecific synthesis of modular ligands based upon cis-1,3-trans-5-substituted cyclohexanes

Content Provider	Semantic Scholar
Author	Fielden, John C. Sprott, Joanna Cronin, Leroy
Copyright Year	2005
Abstract	A range of eight novel ligands, based on the cis-1,3-trans-5-substituted cyclohexane framework, have been synthesized by a stereospecific route starting from cis-1,3,5-cyclohexanetriol. This route depends on the use of efficient mono-silylation and mono-tosylation procedures, is well optimised, and due to isolation of the diazido alcohol precursor cis-3,5-diazido-trans-hydroxycyclohexane readily allows the synthesis of a sizeable family of related ligands via O-derivatisation. Such derivatisations allow systematic changes between various coordinating, hydrogen bonding and lipophilic groups, allowing potential for this ligand system to be utilised in supramolecular coordination chemistry.
Starting Page	1152
Ending Page	1158
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/B503606B
Alternate Webpage(s)	http://www.chem.gla.ac.uk/cronin/media/papers/Fielden2005NJC.pdf
Alternate Webpage(s)	https://doi.org/10.1039/B503606B
Volume Number	29
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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