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Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Rong, Jian Deng, Ling Tan, Ping Cheng Ni, Chuanfa Gu, Yucheng Hu, Jinbo |
| Copyright Year | 2016 |
| Abstract | The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible-light photoredox catalysis. A wide range of readily available mono-, di-, and trifluoromethyl heteroaryl sulfones can thus be used as efficient radical fluoroalkylation reagents under mild conditions. This method not only describes a new synthetic application of fluorinated sulfones, but also provides a new route to fluoroalkyl radicals. |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/anie.201510533 |
| PubMed reference number | 26797782 |
| Journal | Medline |
| Volume Number | 55 |
| Issue Number | 8 |
| Alternate Webpage(s) | http://hujinbo.sioc.ac.cn/userfiles/anie201510533.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/anie.201510533 |
| Journal | Angewandte Chemie |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |