Redox-active ligand uranium complexes for approaches to multi-electron chemistry

Content Provider	Semantic Scholar
Author	Kiernicki, John J.
Copyright Year	2016
Abstract	.................................................................................................................... xiv CHAPTER 1 SYNTHESIS AND CHARACTERIZATION OF A FAMILY OF REDUCED PYRIDINE(DIIMINE) URANIUM COMPLEXES: REACTIVITY TOWARD ONE AND TWO ELECTRON OXIDANTS ....................................................1 1.1 Abstract ....................................................................................................................1 1.2 Introduction ..............................................................................................................2 1.3 Experimental ............................................................................................................3 1.4 Results and Discussion ..........................................................................................15 1.4.1 Synthesis of Reduced Complexes .................................................................15 1.4.2 Reactivity with Carbonylated Substrates ......................................................24 1.4.3 Reactivity Toward Two Electron Oxidants ..................................................35 1.4.4 Reduction of Arylazides ...............................................................................45 1.5 Conclusion .............................................................................................................54 1.6 References ..............................................................................................................55 CHAPTER 2. SYNTHESIS AND CHARACTERIZATION OF URANIUM BIS(IMIDO) COMPLEXES DERIVED FROM THE REDUCTION OF ARYLAZIDES AND DIAZENES BY LOW-VALENT PRECURSORS ........................61 2.1 Abstract ..................................................................................................................61 2.2 Introduction ............................................................................................................63 2.3 Experimental ..........................................................................................................66 2.4 Results and Discussion ..........................................................................................77 2.4.1 Synthesis and Characterization of Bis(imido) Complexes ...........................77 2.4.2 Oxidation of Bis(imido) Complexes .............................................................93 2.4.3 Investigation Into Bis(Imido) Formation Through the Use of Tethered Diazenes .........................................................................................................100
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Language	English
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Resource Type	Article