NDLI: Synergistic gold and enamine catalysis: intermolecular α-alkylation of aldehydes with allenamides.

Content Provider	Semantic Scholar
Author	Fernández-Casado, Jaime Nelson, Ronald Mascareñas, José Luis López, Fernando
Copyright Year	2016
Abstract	Aldehydes can be α-alkylated with allenamides by the combined action of an organocatalyst and a gold complex. The reaction requires the simultaneous generation of an enamine and a gold-activated allenamide. Importantly, by using a chiral amine as organocatalyst it is possible to obtain aldehyde products featuring all-carbon quaternary stereocenter at their α-position, with moderate to good levels of enantioselectivity.
File Format	PDF HTM / HTML
DOI	10.1039/c5cc09533f
PubMed reference number	26765976
Journal	Medline
Volume Number	52
Issue Number	14
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/cc/c5cc09533f/c5cc09533f1.pdf
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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