NDLI: Synthesis of 2‐Alkynoates by Palladium(II)‐Catalyzed Oxidative Carbonylation of Terminal Alkynes and Alcohols

Content Provider	Semantic Scholar
Author	Hughes, N. Louise Muldoon, Mark J.
Copyright Year	2016
Abstract	A homogeneous Pd(II) catalyst, utilizing a simple and inexpensive amine ligand (TMEDA), allows 2-alkynoates to be prepared in high yields by an oxidative carbonylation of terminal alkynes and alcohols. The catalyst system overcomes many of the limitations of previous palladium carbonylation catalysts. It has an increased substrate scope, avoids large excesses of alcohol substrate and uses a desirable solvent. The catalyst employs oxygen as the terminal oxidant and can be operated under safer gas mixtures.
Starting Page	11982
Ending Page	11985
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1002/chem.201602558
PubMed reference number	27305489
Journal	Medline
Volume Number	22
Alternate Webpage(s)	https://pure.qub.ac.uk/portal/files/125523728/synthesis_of_2.pdf
Alternate Webpage(s)	https://pureadmin.qub.ac.uk/ws/portalfiles/portal/125523728/synthesis_of_2.pdf
Alternate Webpage(s)	https://doi.org/10.1002/chem.201602558
Journal	Chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Synthesis of 2‐Alkynoates by Palladium(II)‐Catalyzed Oxidative Carbonylation of Terminal Alkynes and Alcohols