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Rhodium(III)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins through C-H activation.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yang, Tingting Zhang, Tao Yang, Shangdong Chen, Shanshan Li, Xingwei |
| Copyright Year | 2014 |
| Abstract | Rh(III)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins via C-H bond activation is described. Diarylketones were obtained through coupling of N-sulfonyl 2-aminobenzaldehydes with 7-oxabenzonorbornadienes. On the other hand, the coupling with allyl carbonate yielded a six-membered sulfonyl lactam via a sequence of allylation-isomerization-Michael cyclization. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c4ob00704b |
| PubMed reference number | 24838825 |
| Journal | Medline |
| Volume Number | 12 |
| Issue Number | 25 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C4OB00704B |
| Alternate Webpage(s) | https://doi.org/10.1039/c4ob00704b |
| Journal | Organic & biomolecular chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |