NDLI: Copper-catalysed direct radical alkenylation of alkyl bromides.

Content Provider	Semantic Scholar
Author	Zhang, Xu Liao, Zhixiong Zhang, Guoting Fan, Chao Lei, Aiwen
Copyright Year	2014
Abstract	A copper-catalysed direct radical alkenylation of various benzyl bromides and α-carbonyl alkyl bromides has been developed. Compared with the recent radical alkenylations which mostly focused on secondary or tertiary alkyl halides, this transformation shows good reactivity to primary alkyl halides and tertiary, secondary alkyl halides were also tolerated. The key initiation step of this transformation is a copper-induced single-electron reduction of C-Br bonds to generate alkyl radical species.
File Format	PDF HTM / HTML
DOI	10.1039/c4ob00813h
PubMed reference number	25065706
Journal	Medline
Volume Number	12
Issue Number	35
Alternate Webpage(s)	http://www.rsc.org/suppdata/ob/c4/c4ob00813h/c4ob00813h1.pdf
Alternate Webpage(s)	http://pubs.rsc.org/en/content/getauthorversionpdf/C4OB00813H
Alternate Webpage(s)	https://doi.org/10.1039/c4ob00813h
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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