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Tris(ethylenediamine)cobalt(II) bis(tetrahydroxypentaborate) dihydrate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhao, Lizhen Li, Ping Cao, Baoliang |
| Copyright Year | 2009 |
| Abstract | The novel pentaborate with a transition-metal complex as counter-cation and with water of crystallization, tris(ethylenediamine)cobalt(II) bis[4,4',6,6'-tetrahydroxy-2,2'-spirobi(cyclotriboroxane)(1-)] dihydrate, [Co(C(2)H(8)N(2))(3)][B(5)O(6)(OH)(4)](2)·2H(2)O, forms a three-dimensional supra-molecular framework through O-H⋯O hydrogen bonding among the [B(5)O(6)(OH)(4)](-) anions with large channels along the a axis in which the templating [Co(en)(3)](2+) cations (en = ethylenediamine) and water mol-ecules are located. The crystal packing is consolidated by additional O-H⋯O and N-H⋯O hydrogen bonds. |
| Starting Page | m368 |
| Ending Page | m368 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2009/04/00/pv2140/pv2140.pdf |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/d6/3e/e-65-0m368.PMC2968773.pdf |
| PubMed reference number | 21582323 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536809007296 |
| DOI | 10.1107/s1600536809007296 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 65 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Anions Cations Coordination Complexes Crystallization Ethylenediamines Hydrogen Bonding Mole, unit of measurement Pyschological Bonding calcium phosphate, dibasic, dihydrate |
| Content Type | Text |
| Resource Type | Article |
