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Mass‐resolved multiphoton ionization spectroscopy of jet‐cooled Cl2. II. The (2+1) REMPI spectrum between 76 000 and 90 000 cm−1
| Content Provider | Semantic Scholar |
|---|---|
| Author | Al-Kahali, M. S. N. Donovan, Robert J. Lawley, Kenneth P. Ridley, Trevor |
| Copyright Year | 1996 |
| Abstract | The (2+1) resonance‐enhanced multiphoton ionization (REMPI) spectrum of Cl2 has been recorded between 76 000 and 90 000 cm−1. The origins of twenty Rydberg states are located, with the s series (4s−8s) generally exhibiting four Ω components and the d series (3d−5d) two components for each value of n. Vibronic coupling between the β(1g) ion‐pair state and the 3d and 4d (Ω=1) states is pronounced, necessitating the use of mass‐resolved REMPI for the analysis of these vibronically mixed states. |
| Starting Page | 1833 |
| Ending Page | 1838 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1063/1.470980 |
| Volume Number | 104 |
| Alternate Webpage(s) | https://www.research.ed.ac.uk/portal/files/9302614/Mass_resolved_multiphoton_ionization_spectroscopy_of_jet_cooled_Cl2._II._The_2plus1_REMPI_spectrum_between_76_000_and_90_000_cm_1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1063/1.470980 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
