NDLI: Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.

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Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.

Content Provider	Semantic Scholar
Author	Shockley, Samantha E. Hethcox, J. Caleb Stoltz, Brian M.
Copyright Year	2017
Abstract	The first highly enantioselective iridium-catalyzed allylic alkylation that provides access to products bearing an allylic all-carbon quaternary stereogenic center has been developed. The reaction utilizes a masked acyl cyanide (MAC) reagent, which enables the one-pot preparation of α-quaternary carboxylic acids, esters, and amides with a high degree of enantioselectivity. The utility of these products is further explored through a series of diverse product transformations.
Starting Page	11545
Ending Page	11548
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1002/anie.201707015
PubMed reference number	28722280
Journal	Medline
Volume Number	56
Issue Number	38
Alternate Webpage(s)	http://stoltz2.caltech.edu/publications/214-synfact.pdf
Alternate Webpage(s)	https://authors.library.caltech.edu/79196/1/1c1d2bb65e3a8cfe174e374c7132cbdf12579d9b5ca8f3840720a724a04e89de.pdf
Alternate Webpage(s)	http://stoltz2.caltech.edu/publications/213-s-2017.pdf
Alternate Webpage(s)	https://doi.org/10.1002/anie.201707015
Journal	Angewandte Chemie
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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