NDLI: Ruthenium-Catalyzed Oxidative Dearomatization of Indoles for the Construction of C2-Quaternary Indolin-3-ones

Content Provider	Semantic Scholar
Author	Zhou, Xiao-Yu Chen, Xia Wang, Liang-Guang Yang, Dan Li, Jin-Hui
Copyright Year	2018
Abstract	A ruthenium-catalyzed oxidative dearomatization of 2-alkyl- or 2-aryl-substituted indoles has been developed. When coupled with a cascade transformation, it provides a new system for the construction of indolin-3-ones bearing a C2-quaternary functionality. The reaction occurs readily with RuCl3·3H2O as a catalyst in acetonitrile. 2-(3-Indolyl)-substituted indolin-3-ones were obtained in medium to high yields. A mechanism for the reaction is also proposed.
Starting Page	835
Ending Page	839
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1055/s-0036-1591876
Volume Number	29
Alternate Webpage(s)	https://www.thieme-connect.de/media/synlett/201806/supmat/sup_st-2017-w0774-l_10-1055_s-0036-1591876.pdf
Alternate Webpage(s)	https://doi.org/10.1055/s-0036-1591876
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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