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S,O-ligand-promoted palladium-catalyzed C–H olefination of arenes with allylic substrates
| Content Provider | Semantic Scholar |
|---|---|
| Author | Naksomboon, Kananat Alvarez-Casao, Yolanda Uiterweerd, Michiel T. Westerveld, Nick Maciá, Beatriz Fernandez-Ibanez, M. Angeles |
| Copyright Year | 2018 |
| Abstract | An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone. |
| Starting Page | 379 |
| Ending Page | 382 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.tetlet.2017.12.047 |
| Volume Number | 59 |
| Alternate Webpage(s) | https://e-space.mmu.ac.uk/619739/1/1-s2.0-S0040403917315502-main.pdf |
| Alternate Webpage(s) | https://pure.uva.nl/ws/files/27019012/1_s2.0_S0040403917315502_main.pdf |
| Alternate Webpage(s) | https://pure.uva.nl/ws/files/27019010/1_s2.0_S0040403917315502_mmc1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/j.tetlet.2017.12.047 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |