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Cross-Coupling Reaction of Iodo-1,2,3-triazoles Catalyzed by Palladium.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Deng, Juan Wu, Yongming Chen, Q. |
| Copyright Year | 2006 |
| Abstract | Transition metal-catalyzed cross coupling reactions are powerful C–C bond formation methods in organic chemistry, especially between C(sp2) centers at which typical SN substitutions cannot operate. 1 Among them, palladium(0) catalysts are the most important one. During the past two decades, palladium catalysts have emerged as extremely powerful tools for the construction of carbon–carbon, as well as carbon–heteroatom bonds.2 Their popularity stems in part from their tolerance of many functional groups such as carbonyl and hydroxy groups, which allows them to be employed in the synthesis of highly complex molecules3 and industrial chemical process.4 Recently this reaction has been expanded to heteroaromatics such as: pyridines,5 oxazoles,6 thiazoles,6,7 thiophenes,8 benzothiophenes,9 pyrazines,10 furans,11 pyrimidines,12 and triazines.12 However, to the best of our knowledge, there is no report related to the cross-coupling reaction of triazoles, which may be due to the problems associated with the synthesis of halotriazoles. |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chin.200608103 |
| Volume Number | 37 |
| Alternate Webpage(s) | http://www.xiuzhengrd.com/ejournals/pdf/synthesis/doi/10.1055/s-2005-872119.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/chin.200608103 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
