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Intramolecular hydrogen-bonded tertiary phosphines as 1,3,5-triaza-7-phosphaadamantane (PTA) analogues.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ekubo, Allen Tobin Elsegood, Mark R. J. Lake, Andrew John Smith, Michael B. |
| Copyright Year | 2009 |
| Abstract | New cationic trialkylphosphines [P(CH(2)NH(2)R){CH(2)N(R)CH(2)N(R)CH(2)}](+) (R = C(6)H(5)CH(2), a; 4-FC(6)H(4)CH(2), b), as their Cl(-) (1a, 1b), SbF(6)(-) (2a, 2b), and PF(6)(-) (3a, 3b) salts, are described. The phosphine framework is conformationally locked, in the solid state, through pairs of intramolecular N-H...N hydrogen bonds which are maintained in the Ru(II) and Rh(III) complexes 4 and 5. Phosphines 1a-3b can be considered as charged variants of the well-known PTA ligand. |
| Starting Page | 1565 |
| Ending Page | 1571 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://dspace.lboro.ac.uk/dspace-jspui/bitstream/2134/15949/3/Manuscript%20(LUPIN,%20MBSmith).pdf |
| PubMed reference number | 19209936v1 |
| Alternate Webpage(s) | https://doi.org/10.1021/ic801709z |
| DOI | 10.1021/ic801709z |
| Journal | Inorganic chemistry |
| Volume Number | 48 |
| Issue Number | 6 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
