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Elimination vs substitution reaction. A dichotomy between Brønsted-Lowry and Lewis basicity.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Méndez, Francisco Javier Garza Richaud, Arlette Alonso, Jesus Alonso |
| Copyright Year | 2015 |
| Abstract | The Brønsted-Lowry and Lewis basicity dichotomy in the elimination vs substitution reaction competition is analyzed in terms of a novel Brønsted-Lowry-Lewis basicity ωp/e. This new index unifies the dichotomy and explains the competition between elimination and substitution mechanisms of alkyl centers with para-substituted phenols. |
| Starting Page | 1 |
| Ending Page | 22 |
| Page Count | 22 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://uvadoc.uva.es/bitstream/10324/21481/1/Mendez.Organic%20Letters.pdf |
| PubMed reference number | 25634158v1 |
| Alternate Webpage(s) | https://doi.org/10.1021/ol5034628 |
| DOI | 10.1021/ol5034628 |
| Journal | Organic letters |
| Volume Number | 17 |
| Issue Number | 4 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Chemical acidity/alkalinity Excretory function Phenols |
| Content Type | Text |
| Resource Type | Article |