NDLI: Asymmetric synthesis of 2-alkyl-substituted tetrahydroquinolines by an enantioselective aza-Michael reaction.

Content Provider	Semantic Scholar
Author	Taylor, Laura L. Goldberg, Frederick W. Hii, King Kuok Mimi
Copyright Year	2012
Abstract	An optically active tetrahydroquinoline intermediate (5) was prepared in 8 steps from monoprotected ethylene glycol, using a Pd-catalysed aza-Michael reaction to induce chirality. This can be transformed into three Galipea alkaloids (angustureine, galipeine and cuspareine). The proximity of a benzyloxy group is found to exert profound effects in several steps of the synthesis.
File Format	PDF HTM / HTML
DOI	10.1039/c2ob25122a
PubMed reference number	22565504
Journal	Medline
Volume Number	10
Issue Number	22
Alternate Webpage(s)	http://www.rsc.org/suppdata/ob/c2/c2ob25122a/c2ob25122a.pdf
Alternate Webpage(s)	http://spiral.imperial.ac.uk/bitstream/10044/1/11207/4/OBC2012v10p4424.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c2ob25122a
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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