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Unprecedented hexagonal bipyramidal single-ion magnets based on metallacrowns.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Li, Quan-Wen Wan, R. Chen, Yan-Cong Liu, Jiang Wang, L. G. Jia, Jian-Hua Chilton, Nicholas F. Tong, Ming-Liang |
| Copyright Year | 2016 |
| Abstract | Two Ln(iii) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are reported for the first time with the Ln(iii) ion featuring nearly perfect hexagonal bipyramidal LnO8 geometry, with pseudo-D6h symmetry. Magnetic measurements reveal that both behave as single-ion magnets (SIMs), where the slow relaxation is dominated by the Raman mechanism. |
| Starting Page | 13365 |
| Ending Page | 13368 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/cc/c6cc06924j/c6cc06924j1.pdf |
| PubMed reference number | 27785484v1 |
| Volume Number | 52 |
| Issue Number | 91 |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | CDISC SDTM Not Done Terminology Ions Magnet |
| Content Type | Text |
| Resource Type | Article |