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Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y6(μ6-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Mishra, Shashank Jeanneau, Erwann Daniele, Stéphane Hubert-Pfalzgraf, Liliane G. |
| Copyright Year | 2008 |
| Abstract | A colorless polynuclear heterometallic yttrium(III)–copper(I) iodide cluster [Y6(μ6-O)(μ3-OH)8(DMSO)16(H2O)2]8+ [Cu2I4]2−6[I]− (1), isolated in a moderate yield from the hydrolytic reaction of [Y(DMSO)6(DMF)2][CuI3][I] in acetonitrile, undergoes unique crystal-to-crystal transformation to give reddish-yellow cluster [Y6(μ6-O)(μ3-OH)8(DMSO)14(H2O)4]8+ 2[CuI3]2−3[I]− [I3]− (2). |
| Starting Page | 814 |
| Ending Page | 816 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B802434K |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ce/b8/b802434k/b802434k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/B802434K |
| Volume Number | 10 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |